For over a year I’ve been cautioning readers that while lithium-ion batteries are glamorous, sleek, sexy and hot; they are about to face a formidable challenge from lead-carbon batteries that are a little bulkier and heavier, but offer competitive cycle-life and power for a tiny fraction of the cost. To placate lithium fundamentalists and EV evangelists, I want to clearly state up front that lead-carbon batteries will probably not be the first choice for plug-in vehicles. Nevertheless, it is crystal clear that lead-carbon batteries will be the only sensible choice for micro, mild and full hybrid electric vehicles (HEV’s) and many grid connected energy storage applications. A July 30th article from Earth2Tech titled, “Vinod Khosla On Why Lithium-Ion Batteries Are Overhyped” says it all, “The most important thing to remember is economic gravity – the cheapest thing ends up winning.” What do you know; somebody far smarter than me who believes cheap beats cool.
As regular readers know, I recently participated in Infocast’s Storage Week 2009 and served on three discussion panels. The core data for this article came from a slide-show that Patrick T. Moseley PhD, the president of the Advanced Lead-Acid Battery Consortium (ALABC), presented at the conference. While I’ve known about the surprising gains that come from the integration of advanced carbon materials into conventional lead-acid batteries for several years, the Moseley presentation is one of the first public documents to explore the details. A copy of Dr. Moseley’s Storage Week presentation is available here. A complete archive of my articles on the energy storage sector is available here.
The media began paying attention to lead-carbon batteries in January 2008 when Autobloggreen reported the results of a road test that used a split-electrode lead-carbon “Ultrabattery” developed by Australia’s Commonwealth Scientific and Industrial Research Organisation (CSIRO) to power a modified Honda Insight for 100,000 miles. The gist of the report was that in exchange for a weight penalty of 17 kg (37 pounds) and a fuel economy penalty of 2.8%, the Ultrabattery promised to shave up to $2,000 off the sticker price of a mild hybrid. Dr. Moseley’s presentation took the Autobloggreen report a couple steps further and provided the following graph of ALABC-sponsored cycle life testing that compared the Ultrabattery to a standard NiMH battery through 180,000 cycles at discharge rates of up to 5C and recharge rates of up to 4.5C using the European Council for Automotive R&D (EUCAR) Power Assist Profile (click on the graph for a larger image).
Similar cycle-life improvement was clear in another graph from the Moseley presentation that compared the performance of conventional lead-acid batteries with lead-carbon batteries that incorporated 2% carbon black and 2% graphite by weight (roughly 10% carbon by volume) in the sponge lead paste for the negative electrodes (click on the graph for a larger image). This particular series of tests compared the two battery strings at discharge rates of up to 4C and recharge rates of up to 3C using a duty cycle developed by BAE Systems for its hybrid transit bus program. Once again, the cycle-life gains were remarkable.
The real meat and potatoes of the Moseley presentation, however, was a slide that compared the performance and price of the Ultrabattery against (click on the graph for a larger image):
- The Power Assist HEV Battery Goals established by the US Advanced Battery Consortium (USABC);
- An Advanced Automotive Battery Conference (AABC) performance report on NiMH batteries; and
- An AABC forecast on future generations of lithium-ion batteries.
While I hate belaboring the obvious, a simple battery technology that surpasses USABC goals by a comfortable margin while reducing the sticker price of a mild hybrid by up to 10% is important in hard times because the majority of American and European consumers are carefully weighing car buying decisions and demanding real value. More importantly, lead-carbon batteries can be manufactured in existing plants without building a new manufacturing, supply chain and distribution infrastructure from the ground up. As a matter of simple capital efficiency, lead-carbon battery manufacturing will be an order of magnitude cheaper. It can also ramp up to required volumes in years rather than decades.
In a January 2009 article titled “Lead-Carbon: A Game Changer for Alternative Energy Storage” I reprinted a graph that showed the results of a series of partial state of charge (PSOC) cycle-life tests that Sandia National Laboratories performed in 2008 on five different batteries including a valve regulated lead-acid (VRLA) battery, two VRLA batteries with carbon enhanced pastes, an Ultrabattery, and an advanced lithium-ion (Li-FePO4) battery. I also reprinted Sandia’s summary slide which concluded, “The new carbon enhanced negative electrodes in VRLA batteries have dramatically improved utility PSOC cycle-life up to a factor of 10.”
In a follow-up article titled “Lead Carbon Batteries: A Game Changer for Alternative Energy Storage – Part II” I compared the relative strengths and weaknesses of the principal lead-carbon battery developers, both public and private. The four public companies that are actively developing lead-carbon battery technology are:
- MeadWestvaco (MWV), a packaging material and container manufacturing company that is developing carbon additives for the sponge lead pastes used in conventional lead-acid batteries;
- Furukawa Battery Company (Frankfurt – FBB.F), which licensed the Ultrabattery from CSIRO and built the batteries used in the 100,000-mile road test;
- Axion Power International (AXPW.OB) a manufacturer of lead-acid batteries that has built a formidable patent portfolio in lead-carbon battery technology and was recently awarded $380,000 in ALABC grants for lead-carbon research and development; and
- Exide Technologies, Inc. (XIDE), a leading global manufacturer of lead-acid batteries that recently teamed up with Axion for the manufacturing and distribution of products based on Axion’s proprietary lead-carbon technologies.
A 10-fold improvement in the performance of any technology is highly disruptive. The fact that lead-carbon batteries can do the work using cheap and plentiful raw materials from domestic sources and provide a product that is easily recycled in existing facilities is a game changer; particularly when both lithium-ion and NiMH batteries are based on imported raw materials that are likely to face substantial short-term supply constraints and will require the development of new recycling techniques and the establishment of a new recycling infrastructure.
In America we get up in the morning, we go to work and we solve our problems. NiMH and lithium-ion batteries cannot help the auto industry meet accelerated EU tailpipe CO2 emission standards and US CAFE standards because factories to make the batteries do not exist and even if they did the world’s mines couldn’t extract the needed raw materials fast enough to satisfy the demand. Over the next decade there’s a fair chance that lithium-ion batteries will complete the development and testing path described in an unpublished “pre-decisional draft” of a DOE report titled, National Battery Collaborative (NBC) Roadmap, December 9, 2008, which discusses the merits, risks and expected costs of an aggressive eight-year initiative to foster the development and facilitate the commercialization of lithium-ion batteries. However those future advances will have no impact on our current problems.
It’s time to quit talking about the distant future and focus on solving today’s problems.
In closing I want to once again share an image from cartoonist Jan Darasz that was published in the Winter 2008 edition of Batteries International magazine with my article, America Must Rebuild Domestic Battery Manufacturing Infrastructure.
DISCLOSURE: Author is a former director of Axion Power International (AXPW.OB) and holds a large long position in its stock. He also holds a small long position in Exide (XIDE).
John L. Petersen, Esq. is a U.S. lawyer based in Switzerland who works as a partner in the law firm of Fefer Petersen & Cie and represents North American, European and Asian clients, principally in the energy and alternative energy sectors. His international practice is limited to corporate securities and small company finance, where he focuses on guiding small growth-oriented companies through the corporate finance process, beginning with seed stage private placements, continuing through growth stage private financing and concluding with a reverse merger or public offering. Mr. Petersen is a 1979 graduate of the Notre Dame Law School and a 1976 graduate of Arizona State University. He was admitted to the Texas Bar Association in 1980 and licensed to practice as a CPA in 1981.
You make a great point, the Lead Carbon battery certainly is worth watching. However, as you point out these batteries are most useful for hybrids. If alternative energies move swiftly enough then even hybrid vehicles could end up being a thing of the past in preference to hydrogen engines. There are some interviews with researchers and business figures involved in the development of alternative energies at http://www.ourblook.com/component/option,com_sectionex/Itemid,200076/id,8/view,category/#catid92 which is useful on these subjects.
This is all wonderful and good and exciting, but it has been wonderful and good and exciting for many years. Ultra-battery technology has been around and working in labs for years. Where the hell is it? Why is it not accessible now? I would love to buy 13 12 volt 200ah ultra-batteries today! Show me where? All that you have said means NOTHING unless it is available to the consumer or auto manufacturer. Use your ‘stock owner’ influence and get the product to the consumer, please. Thank you for your contribution, now finish the job.
Bill, hydrogen is an ultra-cool fuel but using explosive compressed gasses for transportation fuel is a formidable practical challenge. Even using CNG would be a big step forward from where we are today in terms of both cost and carbon content, but the devil’s in the details. My fondest hope is that some of the new materials we’re reading about in the press will supplant existing battery technologies with something better, but that kind of work takes lots of money and time to get it right; all of which leaves lead-carbon as the best available bridging technology.
Eric, the gulf between a laboratory bench and a factory floor is immense and the industrial engineering to develop new manufacturing methods is always harder than the raw scientific research. Axion has built an automated production line for its PbC batteries and is testing manufactured products before it’s partners begin selling them to customers. Since the first customers are likely to be large OEM’s, it may be a while before you’ll be able to buy them off the shelf at Auto Zone.
Let me suggest that the media began paying attention to lead carbon batteries well before January 2008 as you’ve cited. But two of the many examples of such media articles: Firefly Energy won the worldwide “R&D 100” award in the category of Energy, and the Wall Street Journal “Technology Innovation in Energy” went to Firefly as well for its innovative carbon foam lead acid battery technology.
Good to see that you’ve cited Vinod Khosla’s recent afirmations–he’s an investor in Firefly as well. Perhaps in covering this category in the future, you can expand your readers’ knowledge beyong the “public companies” you’ve often cited, since young companies are often the wellspring for innovation.
Mil, I meant no slight to Firefly but as I understand the Firefly composite foam it’s a structural element that reduces weight and increases energy density rather than an active part of the energy storage function, so it wasn’t really a great fit for this particular article.
I do mention Firefly frequently because I think you’ve got an important emerging technology, but I usually do so with reference to your manufacturing alliance with C&D. In the final analysis, there are a world of fine storage technologies that are being developed by private companies like Firefly. While technical types are interested in everything, financial types only need and want to know about companies that they can invest in.
That being said, if you can get me some detailed information on “what’s happening now” with manufacturing and testing, I’d be delighted to mention Firefly more often.